②6CO2(g)+6H2O(g)=C6H12O6(s)+6O2 △H2
③2H2O(g)=2H2(g)+O2(g) △H3
④2CO2(g)+6H2(g)=C2H5OH(l)+3H2O △H4
下列有关说法正确的是( )
①光催化分解水制氧气:2H2O(l)=2H2(g) + O2(g) ΔH1=+571.6 kJ·mol-1
②过氧化氢分解制氧气:2H2O2(l)=2H2O(l) + O2(g) ΔH2=-196.4 kJ·mol-1
③一氧化氮分解制氧气:2NO(g)=N2(g) + O2(g) ΔH3=-180.5 kJ·mol-1
①CH4(g)+2O2(g)═CO2(g)+2H2O(l)△H1;CH4(g)+2O2(g)═CO2(g)+2H2O(g)△H2;
②S(s)+O2(g)═SO2(g)△H1;S(g)+O2(g)═SO2(g)△H2;
③2H2(g)+O2(g)═2H2O(l)△H1;H2(g)+ O2(g)═H2O(l)△H2;
④CaCO3(s)═CaO(s)+CO2(g)△H1;CaO(s)+H2O(l)═Ca(OH)2(s)△H2 .
N2(g)+3H2O(l)=2NH3(g)+1.5O2(g),△H.
已知:N2(g)+3H2(g)=2NH3(g)△H=a kJ/mol,
2H2(g)+O2(g)=2H2O(l)△H=b kJ/mol,
则N2(g)+3H2O(l)=2NH3(g)+1.5O2(g)的△H=kJ/mol(用含a、b的式子表示).
CO2(g)+3H2(g)⇌CH3OH(g)+H2O(g)△H=Q1kJ•mol﹣1
又查资料得知:①CH3OH(l)+ O2(g)⇌CO2(g)+H2(g)△H=Q2kJ•mol﹣1
②H2O(g)=H2O(I)△H=Q3kJ•mol﹣1
则表示甲醇的燃烧热的热化学方程式为.
用Cl2生产某些含氯有机物时会产生副产物HCl.利用反应A,可实现氯的循环利用.
反应A:4HCl(g)+O2(g) Cl2 (g)+2H2O (g)
已知:Ⅰ.反应A中,4mol HCl被氧化,放出115.6kJ的热量.
Ⅱ.①H2O的电子式是.
②反应A的热化学方程式是.
③断开1mol H﹣O 键与断开 1mol H﹣Cl 键所需能量相差约为 kJ,H2O中H﹣O 键比HCl中H﹣Cl键(填“强”或“弱”).