2018年是合成氨工业先驱哈伯(F•Haber)获得诺贝尔奖100周年。N
2和H
2生成NH
3的反应为:
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmfrac%3E%3Cmrow%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmfrac%3E%3Cmn%3E%26nbsp%3B%3C%2Fmn%3E%3C%2Fmath%3E)
N
2(g)+
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmfrac%3E%3Cmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmfrac%3E%3C%2Fmath%3E)
H
2(g)
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmover%3E%3Cmo%3E%E2%87%8C%3C%2Fmo%3E%3Cmrow%3E%3C%2Fmrow%3E%3C%2Fmover%3E%3C%2Fmath%3E)
NH
3(g) △H(
298K)=-46.2kJ•mol
-1 , 在Fe催化剂作用下的反应历程如下(*表示吸附态)
化学吸附:N2(g)→2N*;H2(g)→2H*
表面反应:N*+H*
NH*;NH*+H*
NH2*;NH2*+H*
NH3*
脱附:NH3*
NH3(g)
其中,N2吸附分解反应活化能高、速率慢,决定了合成氨的整体反应速率。请回答: