如图,三棱柱ABC﹣A1B1C1中,CA=CB,AB=AA1 , ∠BAA1=60°.
(Ⅰ)证明:AB⊥A1C;
(Ⅱ)若平面ABC⊥平面AA1B1B,AB=CB,求直线A1C与平面BB1C1C所成角的正弦值.