室温下,气体M、N、P、Q之间存在如下转化关系:①
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EM%3C%2Fmtext%3E%3Cmtext%3E%E2%87%8C%3C%2Fmtext%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmtext%3EP%3C%2Fmtext%3E%3C%2Fmath%3E)
;②
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EM%3C%2Fmtext%3E%3Cmtext%3E%E2%87%8C%3C%2Fmtext%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmtext%3EQ%3C%2Fmtext%3E%3C%2Fmath%3E)
, 反应①的速率可表示为
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ev%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E1%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3E%3D%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ek%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E1%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EM%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
, 反应②的速率可表示为
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ev%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3E%3D%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ek%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EM%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
, (
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ek%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E1%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmath%3E)
、
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3Ek%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmath%3E)
为速率常数),在容积为10L的密闭容器中,反应体系中组分M、P的物质的量随时间的变化如下表所示:
| 0 | 1min | 2min | 3min | 4min | 5min | 6min |
M(mol) | 1.00 | 0.76 | 0.56 | 0.40 | 0.36 | 0.36 | 0.36 |
P(mol) | 0 | 0.06 | 0.11 | 0.15 | 0.16 | 0.16 | 0.16 |
下列说法正确的是
- A、0~3min时间段内,Q的平均反应速率为
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E0%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmn%3E5%3C%2Fmn%3E%3Cmtext%3Em%3C%2Fmtext%3E%3Cmtext%3Eo%3C%2Fmtext%3E%3Cmtext%3El%3C%2Fmtext%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3EL%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmtext%3Em%3C%2Fmtext%3E%3Cmtext%3Ei%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3En%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
- B、反应开始后,体系中P和Q的浓度之比保持不变
- C、平衡时M生成Q的转化率为36%
- D、反应①的活化能比反应②的活化能低