反应速率v和反应物浓度的关系是用实验方法测定的。化学反应
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EN%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3C%2Fmath%3E)
包含下列两步:①
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EN%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmath%3E)
(慢)、②
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmath%3E)
(快),第一步反应的速率表达式为
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmi%3Ev%3C%2Fmi%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmi%3Ek%3C%2Fmi%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmi%3Ec%3C%2Fmi%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmi%3Em%3C%2Fmi%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmi%3Ec%3C%2Fmi%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmi%3En%3C%2Fmi%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
, 式中k为常数,m、n值可用下表中数据确定。T℃时测得有关实验数据如下:
序号 | c(NO)/(mol/L) | c(H2)/(mol/L) | 速率/(mol/(L·min)) |
I | 0.0060 | 0.0010 | ![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E8%3C%2Fmn%3E%3Cmo%3E%C3%97%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmsup%3E%3Cmrow%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
|
II | 0.0060 | 0.0020 | ![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E6%3C%2Fmn%3E%3Cmo%3E%C3%97%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmsup%3E%3Cmrow%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
|
III | 0.0010 | 0.0060 | ![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E0%3C%2Fmn%3E%3Cmo%3E%C3%97%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmsup%3E%3Cmrow%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E5%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
|
IV | 0.0020 | 0.0060 | ![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmo%3E%C3%97%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmsup%3E%3Cmrow%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
|
下列说法正确的是( )
- A、整个反应速率由第②步反应决定
- B、分步反应的活化能大小:①<②
- C、反应①速率表达式:
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmi%3Ev%3C%2Fmi%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmn%3E5%3C%2Fmn%3E%3Cmn%3E0%3C%2Fmn%3E%3Cmn%3E0%3C%2Fmn%3E%3Cmn%3E0%3C%2Fmn%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmi%3Ec%3C%2Fmi%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmn%3E%28%3C%2Fmn%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E%29%3C%2Fmn%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmi%3Ec%3C%2Fmi%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
- D、相同条件下,浓度对反应速率的影响:
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmo%3E%26gt%3B%3C%2Fmo%3E%3Cmtext%3EN%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmath%3E)