硼酸(H
3BO
3)在水溶液中存在电离平衡:H
3BO
3+H
2O
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3E%E2%87%8C%3C%2Fmtext%3E%3C%2Fmath%3E)
[B(OH)
4]
-+ H
+ ![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmi%3EK%3C%2Fmi%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3Cmsup%3E%3Cmrow%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E9%3C%2Fmn%3E%3Cmn%3E.%3C%2Fmn%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
, 用0.01 mol/LNaOH溶液分别滴定体积均为20 mL的0.01 mol/L硼酸溶液、0.01 mol/L硼酸和甘露醇混合溶液,滴定过程中硼酸溶液pH、混合溶液的
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmfrac%3E%3Cmrow%3E%3Cmtext%3E%CE%94%3C%2Fmtext%3E%3Cmtext%3Ep%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E%CE%94%3C%2Fmtext%3E%3Cmtext%3EV%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmfrac%3E%3C%2Fmath%3E)
随加入的NaOH溶液体积的变化如图。
已知:
。
![](http://tikupic.21cnjy.com/2024/05/21/4d/7f/4d7f6588329f5e3dae54cc11ff6ae0e9.png)
下列说法正确的是( )
- A、溶液中c(H+):M点<N点
- B、加入甘露醇促进硼酸电离平衡逆向移动
- C、W点:c(Na+)+c(H+)+c(H3BO3)-c(OH-)=0.01 mol/L
- D、P点:
![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3EB%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmtext%3E%3D%3C%2Fmtext%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%7B%3C%2Fmo%3E%3Cmrow%3E%3Cmsup%3E%3Cmrow%3E%3Cmrow%3E%3Cmo%3E%5B%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EB%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E4%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3Cmo%3E%5D%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E-%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3Cmo%3E%7D%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmtext%3E%26gt%3B%3C%2Fmtext%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E-%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmtext%3E%26gt%3B%3C%2Fmtext%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)